Visual Basic.NET Hotmail/MSN Live POP3 server address is "pop3.live.com". It requires SSL connection on 995 port, and you should use your Hotmail/MSN email address as the user name for user authentication. For example: your email is "liveid@hotmail.com", and then the user name should be "liveid@hotmail.com".
The following example codes demonstrate how to retrieve email from Hotmail/MSN Live POP3 server.
' The following example codes demonstrate retrieving email from Hotmail/MSN Live POP3 server
' To get full sample projects, please download and install EAGetMail on your machine.
' To run it correctly, please change email server, user, password, folder, file name value to yours
Imports System.IO 
' Imports EAGetMail namespace
Imports EAGetMail 
Module Module1 
    Sub Main() 
        ' Create a folder named "inbox" under current directory
        ' to save the email retrieved.
        Dim curpath As String = Directory.GetCurrentDirectory() 
        Dim mailbox As String = [String].Format("{0}\inbox", curpath) 
        ' If the folder is not existed, create it.
        If Not Directory.Exists(mailbox) Then 
            Directory.CreateDirectory(mailbox) 
        End If 
        ' Hotmail POP3 server is "pop3.live.com"
        Dim oServer As New MailServer("pop3.live.com", _ 
            "hotmailid@hotmail.com", "yourpassword", ServerProtocol.Pop3) 
        Dim oClient As New MailClient("TryIt") 
        ' Enable SSL connection
        oServer.SSLConnection = True 
        ' Set 995 port
        oServer.Port = 995 
        Try 
            oClient.Connect(oServer) 
            Dim infos As MailInfo() = oClient.GetMailInfos() 
            For i As Integer = 0 To infos.Length - 1 
                Dim info As MailInfo = infos(i) 
                Console.WriteLine("Index: {0}; Size: {1}; UIDL: {2}", _ 
                        info.Index, info.Size, info.UIDL) 
                ' Receive email from POP3 server
                Dim oMail As Mail = oClient.GetMail(info) 
                Console.WriteLine("From: {0}", oMail.From.ToString()) 
                Console.WriteLine("Subject: {0}" & vbCr & vbLf, oMail.Subject) 
                ' Generate an email file name based on date time.
                Dim d As System.DateTime = System.DateTime.Now 
                Dim cur As New System.Globalization.CultureInfo("en-US") 
                Dim sdate As String = d.ToString("yyyyMMddHHmmss", cur) 
                Dim fileName As String = [String].Format("{0}\{1}{2}{3}.eml", _ 
                     mailbox, sdate, d.Millisecond.ToString("d3"), i) 
                ' Save email to local disk
                oMail.SaveAs(fileName, True) 
                ' Mark email as deleted in Hotmail Account
                oClient.Delete(info) 
            Next 
            ' Quit and pure emails marked as deleted from Hotmail POP3 server.
            oClient.Quit() 
        Catch ep As Exception 
            Console.WriteLine(ep.Message) 
        End Try 
    End Sub 
End Module 
If you have any comments or questions about above example codes, please add your comments here.